$ - top of the list to be made. # - I have all/some of the images. % - will be getting images soon.

Movie version unless stated otherwise.

Just to inform you, I have Daredevil, both X-men movies and both Spider-man movies on dvd so I can easily get images for those.

Batman (Beyond)
Justice League (animated) (as individual characters)
X-men (movie)
   -Rogue $%
   -Cyclops
   -Professor Xavier
   -Jean Grey
   -Iceman $%
   -Pyro (should he be a villain?!)
   -Nightcrawler
X-men (comic)
   -Storm
   -Cyclops
   -Professor Xavier
   -Jean Grey $%
   -Wolverine
X-men (animated) - as above
X-men Evolution
Spider-man (comic)
Spider-man (animated)
Hellboy
Superman (original films)
Superman (new film)
Superman (new adventures of/Lois and Clark (that's what it was in the USA right?))
Bird of Prey (if anyone could find images for this shortlived series!)
Phantom
Fantastic Four (comic)
Fantastic Four (animated)
Teen Titans Characters.
Robin (from Batman Forever and Batman and Robin)

Alfred Pennyworth (Batman Begins) #
Matt Murdock
Clark Kent (Smallville)
Peter Parker
Franklin Nelson
Ben Ulrich
Harry Osborn
Norman Osborn
Dick Grayson

Elektra Villains #
Kingpin #
Toad
Magneto
Sabretooth
Doc Ock $%
Poison Ivy (comic) #
Harley Quinn (comic) #

Daredevil vs Bullseye #
Spiderman vs Doc Ock $%
Elektra vs Bullseye
Daredevil vs Elektra (roof top)
Matt Murdock vs Eletra (playground)
Fantastic Four vs Dr Doom
Wolverine vs Deathstrike
Batman vs Ra's Al Ghul

Characters of Sin City (in misc. because none are really 'heroes' in a strict sense)
Punisher (could he be considered a hero or villain? I don't know Punisher well)

Spider-man 2 intro sketches
Batman through the Ages
Batman and Robin storyboard
Batman Beyond storyboard
Stan Lee's Cameos